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  1. SUMMARY

    Yasur volcano, Vanuatu is a continuously active open-vent basaltic-andesite stratocone with persistent and long-lived eruptive activity. We present results from a seismo-acoustic field experiment at Yasur, providing locally dense broad-band seismic and infrasonic network coverage from 2016 July 27 to August 3. We corroborate our seismo-acoustic observations with coincident video data from cameras deployed at the crater and on an unoccupied aircraft system (UAS). The waveforms contain a profusion of signals reflecting Yasur’s rapidly occurring and persistent explosive activity. The typical infrasonic signature of Yasur explosions is a classic short-duration and often asymmetric explosion waveform characterized by a sharp compressive onset and wideband frequency content. The dominant seismic signals are numerous repetitive very-long-period (VLP) signals with periods of ∼2–10 s. The VLP seismic events are ‘high-rate’, reoccurring near-continuously throughout the data set with short interevent times (∼20–60 s). We observe variability in the synchronization of seismic VLP and acoustic sources. Explosion events clearly delineated by infrasonic waveforms are underlain by seismic VLPs. However, strong seismic VLPs also occur with only a weak infrasonic expression. Multiplet analysis of the seismic VLPs reveals a systematic progression in the seismo-acoustic source decoupling. The same dominant seismic VLP multiplet occurs with and without surficial explosions and infrasound, and these transitions occur over a timescale of a few days during our field campaign. We subsequently employ template matching, stacking, and full-waveform inversion to image the source mechanism of the dominant VLP multiplet. Inversion of the dominant VLP multiplet stack points to a composite source consisting of either a dual-crack (plus forces) or pipe-crack (plus forces) mechanism. The derived mechanisms correspond to a point-source directly beneath the summit vents with centroid depths in the range ∼900–1000 m below topography. All mechanisms suggest a northeast trending crack dipping relatively shallowly to the northwest and indicate a VLP source centroid and mechanism controlled by a stable structural geologic feature beneath Yasur. We interpret the results in the framework of gas slug ascent through the conduit responsible for Yasur explosions. The VLP mechanism and timing with infrasound (when present) are explained by a shallow-buffered top-down model in which slug ascent is relatively aseismic until reaching the base of a shallow section. Slug disruption in this shallow zone triggers a pressure disturbance that propagates downward and couples at the conduit base (VLP centroid). If the shallow section is open, an explosion propagates to the surface, producing infrasound. In the case of (the same multiplet) VLPs occurring without surficial explosions and weak or no infrasound, the decoupling of the dominant VLPs at ∼900–1000 m depth from surficial explosions and infrasound strongly indicates buffering of the terminal slug ascent. This buffering could be achieved by a variety of conditions at or directly beneath the vents, such as a high-viscosity layer of crystal-rich magma, a debris cap from backfill, a foam layer, or a combination of these. The dominant VLP at Yasur captured by our experiment has a source depth and mechanism separated from surface processes and is stable over time.

     
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  2. Abstract

    Aerosol deposition with gas phase‐synthesized chain‐like nanoaggregates can yield dense coatings from the impaction of particles on a substrate; however, dense coating formation is not well understood. Here, we study coating consolidation at the single nanoaggregate level. Flame spray pyrolysis‐made tin oxide nanoaggregates are mobility (size) filtered, accelerated through a de Laval nozzle, and impacted on alumina substrates. TEM images obtained from low velocity collection and supersonic deposition are compared via quantitative image analysis, which reveals that upon supersonic impact nanoaggregates fragment into smaller aggregates. This suggests that fragmentation is a key step in producing coatings denser than the depositing nanoaggregates themselves. We supplement experiments with detailed particle trajectory calculations, which show that the impact energies per atom during nanoaggregate deposition are below 0.2 eV/molecule. These results suggest that fragmentation can only occur at locations where nanoaggregates bonded by van der Waals and capillary interactions.

     
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